質子交換膜燃料電池用不銹鋼雙極板氮化Cr鍍層的耐蝕性
Corrosion Resistance of Cr Coating Treated by Nitriding on Stainless Steel Bipolar Plate for Proton Exchange Membrane Fuel Cell
摘 要
采用液相等離子體電解滲氮技術在鍍有純Cr鍍層的316L不銹鋼雙極板上進行短時的氮化處理。采用掃描電子顯微鏡、X射線衍射儀等對Cr氮化鍍層的形貌和成分進行了表征,采用電化學試驗測試了其耐蝕性,并測量了鍍層的界面接觸電阻(RIC)。結果表明:Cr氮化鍍層的表面呈現出凹凸不平的胞狀結構、層鍍為非晶相結構;與基體試樣相比,Cr氮化鍍層的腐蝕電位明顯更高(約為+600 mV),腐蝕電流密度比不銹鋼基體降低兩個數量級,耐蝕效率為99.67%;Cr氮化鍍層的RIC為13.7 mΩ·cm2,導電性能良好。
液相等離子體滲氮
不銹鋼雙極板
耐蝕性
導電性
electrodeposition
liquid phase plasma electrolytic nitriding
stainless steel bipolar plate
corrosion resistance
electrical conductivity
Abstract
The liquid phase plasma electrolytic nitriding technology was used to conduct short-term nitriding treatment on 316L stainless steel bipolar plate with pure Cr coating.The morphology and composition of Cr nitrided coating were characterized by scanning electron microscope and X-ray diffraction. Its corrosion resistance was tested by electrochemical test, and the interface contact resistance (RIC) of the coating was measured. The results showed that the surface of Cr nitrided coating presented uneven cellular structure, and the coating was amorphous structure. Compared with substrate sample, the corrosion potential of Cr nitrided coating was significantly high (about +600 mV), the corrosion current density was two orders of magnitude lower than that of stainless steel substrate, and the corrosion resistance efficiency was 99.67%. The RIC of Cr nitrided coating was 13.7 mΩ·cm2, which had good conductivity.
中圖分類號 TG174 DOI 10.11973/fsyfh-202304001
所屬欄目 試驗研究
基金項目 上海市科委項目(18511110902);國家自然科學基金(21972090)
收稿日期 2021/5/25
修改稿日期
網絡出版日期
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引用該論文: ZHU Yanyan,SHEN Xixun,WANG Tao,DENG Chengwei,XU Qunjie. Corrosion Resistance of Cr Coating Treated by Nitriding on Stainless Steel Bipolar Plate for Proton Exchange Membrane Fuel Cell[J]. Corrosion & Protection, 2023, 44(4): 1
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【3】KHAN M F,ADESINA A Y,GASEM Z M. Electrochemical and electrical resistance behavior of cathodic arc PVD TiN,CrN,AlCrN,and AlTiN coatings in simulated proton exchange membrane fuel cell environment[J]. Materials and Corrosion,2019,70(2):281-292.
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【9】JIN J,HE Z,ZHAO X. Formation of a protective TiN layer by liquid phase plasma electrolytic nitridation on Ti-6Al-4V bipolar plates for PEMFC[J]. International Journal of Hydrogen Energy,2020,45(22):12489-12500.
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【12】CUI J,JING B,XU X,et al. Performance of niobium nitride-modified AISI316L stainless steel as bipolar plates for direct formic acid fuel cells[J]. International Journal of Hydrogen Energy,2017,42(16):11830-11837.
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【16】LI Y,BI Y J,ZHANG M Y,et al. Hollow cathodic plasma source nitriding of AISI 4140 steel[J]. Surface Engineering,2021,37(3):351-359.
【17】NIKOLOV K,BUNK K,JUNG A,et al. Combined plasma surface modification of austenitic stainless steel for bipolar plates[J]. Surface and Coatings Technology,2017,328:142-151.
【18】WANG L,NAM K S,KWON S C. Transmission electron microscopy study of plasma nitriding of electroplated chromium coating[J]. Applied Surface Science,2003,207(1/4):372-377.
【19】WANG H,BRADY M P,TEETER G,et al. Thermally nitrided stainless steels for polymer electrolyte membrane fuel cell bipolar plates[J]. Journal of Power Sources,2004,138(1/2):86-93.
【20】WU J,WANG K,FAN L,et al. Investigation of anodic plasma electrolytic carbonitriding on medium carbon steel[J]. Surface and Coatings Technology,2017,313:288-293.
【21】WU J,FAN L,DONG L,et al. Cathodic plasma electrolysis for preparation of diamond-like carbon particles in glycerol solution[J]. Materials Chemistry and Physics,2017,199:289-294.
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【28】鄭有昌,任鵬煒,唐興穎,等. 表面處理對Alloy 825合金在超臨界水中耐腐蝕性能的影響[J]. 腐蝕與防護,2021,42(2):19-26.
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